@LSA hello,
as @gabo.lr has explained very well,
(as VLL also used for geographically isolated user sites? and VLL is also implemented/used on MPLS Network ?) yes, VLL is a L2VPN, so it could connect the geographically isolated users' sites, and it's also based on MPLS.
I posted a thread about the VPN classification, you might refer it.
For the rest concepts, AC(attachment circuit) indicates the link between CE and PE.
VC(virtual circuit) indicates the logical link between two PEs.
PS, if you mean PW(pseudo wire), it indicates a pair VC between two PEs, it contains two VC which has the inverse directional.